Submissions from 2023
Rapid Generation of P(V)-F Bonds Through the Use of Sulfone Iminium Fluoride Reagents, Lucy P. Miller, James A. Vogel, Shiraz Harel, Jenna M. Krussman, and Patrick R. Melvin
A Modified Beckmann Rearrangement for the Facile Synthesis of Amidines and Imidates via Imidoyl Fluoride Intermediates , James A. Vogel, Kirya Miller, Eunjeong Shin, Jenna Krussman, and Patrick R. Melvin
Submissions from 2022
Protonation and Non-Innocent Ligand Behavior in Pyranopterin Dithiolene Molybdenum Complexes, Cassandra Gates, Haley Varnum, Catherine Getty, Natalie Loui, Ju Chen, Martin L. Kirk, Jing Yang, and Sharon J. Nieter Burgmayer
Catalytic Enantioselective Birch–Heck Sequence for the Synthesis of Phenanthridinone Derivatives with an All-Carbon Quaternary Stereocenter, Mary Elizabeth Sexton, William Paul Malachowski, Glenn P. A. Yap, Diana Rachii, Greg Feldman, Andrew T. Krasley, Zhilin Chen, My Anh Tran, Kalyn Wiley, Alexandra Matei, Samantha Petersen, and Sabrina Tran Tien
Synthesis of Highly Reactive Sulfone Iminium Fluorides and Their Use in Deoxyfluorination and Sulfur Fluoride Exchange Chemistry, James A. Vogel, Rania Hammami, Ara Ko, Hiya Datta, Yael N. Eiben, Karley J. Labenne, Ellis C. McCarver, Ebrar Z. Yilmaz, and Patrick R. Melvin
Submissions from 2018
Catalytic Enantioselective Birch–Heck Sequence for the Synthesis of Tricyclic Structures with All-Carbon Quaternary Stereocenters, Andrew T. Krasley, William Paul Malachowski, Hannah M. Terz, and Sabrina Tran Tien
Structural insight into substrate and product binding in an archaeal mevalonate kinase, Bradley R. Miller and Yan Kung
Structural features and domain movements controlling substrate binding and cofactor specificity in class II HMG-CoA reductase, Bradley R. Miller and Yan Kung
Indoleamine 2,3-Dioxygenase and Its Therapeutic Inhibition in Cancer, George C. Prendergast, William Paul Malachowski, Arpita Mondal, Peggy Scherle, and Alexander J. Muller
Submissions from 2016
Structural elements of an NRPS cyclization domain and its intermodule docking domain, Daniel P. Dowling, Yan Kung, Anna K. Croft, Koli Taghizadeh, Wendy L. Kelly, Christopher T. Walsh, and Catherine L. Drennan
O-Alkylhydroxylamines as Rationally-designed Mechanism-based Inhibitors of Indoleamine 2,3-Dioxygenase-1, William Paul Malachowski, Maria Winters, James B. DuHadaway, Ariel Lewis-Ballester, Shorouk Badir, Maisha Rahman, Eesha Sheikh, Judith M. LaLonde, Syun-Ru Yeh, George C. Prendergast, and Alexander J. Muller
A non-traditional approach to synthesizing aryl vinyl sulfides is described. 2,2-diphenyl-1,3-oxathiolane slowly liberates vinyl sulfide anion under basic conditions. Using a Pd/Xantphos catalyst system to activate a wide range of aryl bromides, this transient sulfide species can be effectively trapped and fed into a traditional Pd0/PdII catalytic cycle. Scope and limitations of the methodology are presented along with significant discussion of a competitive C–S bond activation by this catalyst system., Jason R. Schmink, Summer A. Baker Dockrey, Tianyi Zhang, Naomi Chebet, Alexis van Venrooy, Mary Sexton, Sarah I. Lew, Steffany Chou, and Ami Okazaki
Submissions from 2015
The Enantioselective Construction of Tetracyclic Diterpene Skeletons with Friedel-Crafts Alkylation and Palladium-catalyzed Cycloalkenylation Reactions, Sarah J. Burke, William Paul Malachowski, Sharan K. Mehta, and Roselyn Appenteng
The first report of Lewis acid reagents in the intramolecular Rauhut-Currier reaction, Andrew T. Krasley and William Paul Malachowski
Submissions from 2014
Palladium-Catalyzed Cross-Coupling of 2-Aryl-1,3-Dithianes, Summer Baker Dockrey, Alicia K. Makepeace, and Jason R. Schmink
Constructing tailored isoprenoid products by structure-guided modification of geranylgeranyl reductase, Yan Kung, Ryan P. McAndrew, Xinkai Xie, Charlie C. Liu, Jose H. Pereira, Paul D. Adams, and Jay D. Keasling
Learning About Being a Scientist from the Vitamin B-12 Structure Collaboration, Susan White
Events from 2013
Bringing Online Peer Review into Blended Teaching, Susan White
Submissions from 2012
Structure and Reversible Pyran Formation in Molybdenum Pyranopterin Dithiolene Models of the Molybdenum Cofactor, Benjamin R. Williams, Yichun Fu, Glen P. A. Yap, and Sharon J. Nieter Burgmayer
Submissions from 2011
A Study of Mo(4+)Quinoxalyl-Dithiolenes as Models for the Non-Innocent Pyranopterin in the Molybdenum Cofactor, Kelly G. Matz, Regina P. Mte, Rebecca Rothstein, Martin L. Kirk, and Sharon J. Nieter Burgmayer
Submissions from 2010
Carbonate Control of H(2) and Ch(4) Production in Serpentinization Systems at Elevated P-Ts, L. Camille Jones, Robert Rosenbauer, Jonas I. Goldsmith, and Christopher Oze
Noninnocent Dithiolene Ligands: A New Oxomolybdenum Complex Possessing a Donor-Acceptor Dithiolene Ligand, Kelly G. Matz, Regina P. Mtei, Belinda Leung, Sharon J. Nieter Burgmayer, and Martin L. Kirk
Enantioselective Synthesis of Bicarbocyclic Structures with an All-Carbon Quaternary Stereocenter Through Sequential Cross Metathesis and Intramolecular Rauhut-Currier Reaction, Yuan Qiao, Sanjeev Kumar, and William Paul Malachowski
Submissions from 2008
The Quenching of Isopropyl Group Rotation in Van Der Waals Molecular Solids, Xianlong Wang, Arnold L. Rheingold, Antonio G. DiPasquale, Frank B. Mallory, Clelia W. Mallory, and Peter A. Beckmann
Submissions from 2007
Synthesis, Characterization, and Spectroscopy of Model Molybdopterin Complexes, Sharon J. Nieter Burgmayer, Mary Kim, Rebecca Petit, Amy Rothkopf, Shadia BelHamdounia, Ying Hou, Arpad Somogyi, Diana Habel-Rodriguez, Antonio Williams, and Martin L. Kirk
Submissions from 2004
Sequential Birch Reduction-Allylation and Cope Rearrangement of O-Anisic Acid Derivatives, William Paul Malachowski and Marisha Banerji
Redox Reactions of the Pyranopterin System of the Molybdenum Cofactor, Sharon J. Nieter Burgmayer, Dori L. Pearsall, Shannon M. Blaney, Eva M. Moore, and Calies Sauk-Schubert
Submissions from 2003
Methyl and T-Butyl Group Reorientation in Planar Aromatic Solids: Low-Frequency Nuclear Magnetic Resonance Relaxometry and X-Ray Diffraction, Peter A. Beckmann, Carylon Buser, Kathleen Gullifer, Frank B. Mallory, Clelia W. Mallory, Gene M. Rossi, and Arnold L. Rheingold
Submissions from 2002
The Crystal Packing of 4,7-Dichloro- and 4,7-Dibromobenzo[C]Furazan 1-Oxide, D. Britton, Frank B. Mallory, and C. W. Mallory
Submissions from 1994
Competing C–Br and C–C Bond Fission Following 1[n(O),π∗(C=O)] Excitation in Bromoacetone: Conformation Dependence of Nonadiabaticity at a Conical Intersection, P. W. Kash, G.C.G. Waschewsky, R. E. Morss, L. J. Butler, and Michelle M. Francl
Submissions from 1993
Distance Dependence of Nonadiabaticity in the Branching Between C–Br and C–Cl Bond Fission Following 1[n(O),π∗(C=O)] Excitation in Bromopropionyl Chloride, P. W. Kash, G.C.G. Waschewsky, L. J. Butler, and Michelle M. Francl
Submissions from 1987
Methyl Reorientation in Methylphenanthrenes: 1. Solid-State Proton Spin-Lattice Relaxation in the 3-Methyl, 9-Methyl, and 3,9-Dimethyl Systems, K. G. Conn, Peter A. Beckmann, C. W. Mallory, and Frank B. Mallory
Submissions from 1982
Self‐consistent molecular orbital methods. XXIII. A polarization‐type basis set for second‐row elements, Michelle M. Francl, William J. Pietro, Warren J. Hehre, J Stephen Binkley, Mark S. Gordon, Douglas J. DeFrees, and John A. Pople