"The first report of Lewis acid reagents in the intramolecular Rauhut-C" by Andrew T. Krasley and William Paul Malachowski
 

Document Type

Article

Version

Author's Final Manuscript

Publication Title

Tetrahedron Letters

Volume

56

Publication Date

2015

Abstract

The first report of Lewis acid use in intramolecular Rauhut-Currier reactions is described. Titanium Lewis acids lead to rapid Rauhut-Currier reactions in the case of two classic substrates. More importantly, titanium and tin Lewis acids were the only successful reagent for a more complex substrate, thereby illustrating the potential for Lewis acid reagents to facilitate challenging intramolecular Rauhut-Currier reactions that fail with traditional reagents.

DOI

10.1016/j.tetlet.2015.09.069

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