Physical Review B
We reinterpret proton spin-lattice relaxation measurements in solid 1,4-di-t-butylbenzene (1,4-DTB) [P. A. Beckmann, F. A. Fusco, and A. E. O'Neill, J. Magn. Reson. 59 63 (1984)] in light of a recent study of solid 1,3-DTB [P. A. Beckmann, A. I. Hill, E. B. Kohler, and H. Yu, Phys. Rev. B 38 11098 (1988))]. We investigate the relationship between the spectral density that characterizes the intramolecular reorientation of the t-butyl groups and their constituent methyl groups in DTB, and the t-butyl group environment which dictates the symmetry of the local electrostatic potential. For both isomers, if one assumes a sixfold potential, then a spectral density characteristic of a distribution of correlation times (or a nonexponential correlation function) is required, but if one assumes a lower, threefold symmetry due to crystal effects (for both isomers) or due to intramolecular effects (for the 1,3-isomer), then the relaxation-rate data can be interpreted in terms of a unique correlation time for intramolecular reorientation. For the case where only methyl groups are reorienting (i.e., either no t-butyl group reorientation or no t-butyl groups at all) one can only use the model which characterizes the reorientation in terms of a distribution of correlation times (or a nonexponential correlation function). Recent work in methyl-substituted phenanthrenes [K. G. Conn, P. A. Beckmann, C. W. Mallory, and F. B. Mallory, J. Chem. Phys. 87 20 (1987)] is used to make the latter point.
© 1989 by the American Physical Society. The publisher's version of the article can be found at http://link.aps.org/doi/10.1103/PhysRevB.39.12248.
Peter A. Beckmann. Phys. Rev. B 39, 12248 (1989).