Document Type
Article
Version
Author's Final Manuscript
Publication Title
Solid State Nuclear Magnetic Resonance
Volume
71
Publication Date
2015
Abstract
We report a quantitative measure of the nonexponential 1H spin-lattice relaxation resulting from methyl group (CH3) rotation in six polycrystalline van der Waals solids. We briefly review the subject in general to put the report in context. We then summarize several significant issues to consider when reporting 1H or 19F spin-lattice relaxation measurements when the relaxation is resulting from the rotation of a CH3 or CF3 group in a molecular solid.
Publisher's Statement
© 2015. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Citation
Nonexponential 1H spin-lattice relaxation and methyl group rotation in molecular solids. P. A. Beckmann 2015 Solid State Nuclear Magnetic Resonance 71 91-95.
DOI
10.1016/j.ssnmr.2015.07.001